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This sustained elevation is what inhibits melanogenesis: glutathione competitively inhibits tyrosinase (the rate-limiting enzyme in melanin synthesis) and shifts melanin production from eumelanin (brown-black pigment) toward pheomelanin (red-yellow pigment), resulting in visible skin lightening over 612 weeks of biweekly administration

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Incubation with 13 C 3 -serine as an extracellular serine source for 6 h resulted in almost complete labeling of the intracellular serine pool (Fig