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Its evolution may have occurred in association with the Great Oxidation Event (2.5-2.0 bya) when the Earths atmospheric concentrations of oxygen rose profoundly because of its release from the photosynthesizing microbes, cyanobacteria ( Figure 2 ) (62, 63)

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Physiol Res 59:177185 Tanokura M, Tasumi M, Miyazawa T (1976) 1 H nuclear magnetic resonance studies of histidine containing di and tripeptides